2009
DOI: 10.1007/s11814-009-0051-8
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Enthalpy profile-cure state relationship of compounded rubber by differential scanning calorimetry

Abstract: Differential scanning calorimetry (DSC) was applied to natural rubber (NR) and NR/recycled natural rubber (RNR)(NR/RNR) blend to understand and optimize the state of cure, which is based on the value of the exothermic reaction obtained in process of vulcanization. Swelling and mechanical data were investigated with the increase of cure time from 15 to 35 minutes with an interval of 5 minutes and compared with the DSC enthalpy data. With the increasing cure time, cure enthalpy was decreased and a negative, whil… Show more

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Cited by 3 publications
(2 citation statements)
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“…Residual heat of vulcanization (1 À X n ) is proportional to the unreacted cure system. 8 Cure reaction was investigated under nitrogen atmosphere by TA Instruments Q100 DSC (Milan, Italy), calibrated with melt purity indium standard (156.6 C and 28.45 J g À1 ). Samples with a mass of about 5 mg are used.…”
Section: Cure Kineticmentioning
confidence: 99%
“…Residual heat of vulcanization (1 À X n ) is proportional to the unreacted cure system. 8 Cure reaction was investigated under nitrogen atmosphere by TA Instruments Q100 DSC (Milan, Italy), calibrated with melt purity indium standard (156.6 C and 28.45 J g À1 ). Samples with a mass of about 5 mg are used.…”
Section: Cure Kineticmentioning
confidence: 99%
“…16 Cure reaction was investigated in nitrogen atmosphere by TA Instrument Q100 DSC, calibrated with melt purity indium standard (156.6 C and 28.45 J/g). Samples with a mass of about 5 mg are used.…”
Section: Cure Kineticmentioning
confidence: 99%