The objectives of present work emphasize the successful usage of Fe(III) modified layered double
hydroxide clays with reduced graphene support (Si-rGO/LDH-Fe) for the removal of V(V) and Se(IV)
from aqueous systems. The precursors along with the modified and sorbent loaded materials were
successfully characterized by BET surface area analyzer, SEM-EDS mapping, FTIR, potentiometric
titrations and XPS analysis. Sorption performance of Si-rGO/LDH-Fe towards V(V) and Se(IV) under
optimized conditions such as pH, temperature and concentration were investigated. The equilibrium
and kinetic investigations revealed that the adsorption of V(V) and Se(IV) onto Si-rGO/LDH-Fe follows
non-linear Langmuir isotherm and pseudo-second-order model, respectively. The equilibrium reached
within 120 min and the Langmuir isotherm fit well with the experimental data. The adsorption
mechanism was proposed to be ligand exchange with electrostatic interactions. Such results indicated
that V(V) and Se(IV) species interact by the protonated hydroxyl moieties on the surface of
Si-rGO/LDH-Fe. The practical efficacy and effectiveness of Si-rGO/LDH-Fe was also compared with
some of the related works reported so far. The regeneration capacity and reusability of Si-rGO/LDH-Fe
were also tested by employing four cycles of desorption experiments.