We present experimental evidence for a deceleration of convoy electrons produced by 5 MeV͞u ions (N 71 , Ne 101 , S 131 , Ni 231 , and Ag 371 ) during the interaction with insulator foils at normal incidence. The deceleration first increases with increasing projectile charge, reaches a maximum at a projectile charge of about 16, and seems to approach zero for even higher charges. Different possible mechanisms and quantitative estimates for the slowing down of convoy electrons are presented.[ S0031-9007(97) PACS numbers: 34.50. Fa, 72.20.Jv, 73.61.Ph, 79.20.Rf Electron spectra in ion-solid interactions show, apart from Auger lines and binary-encounter electrons, one prominent structure exactly in the projectile flight direction: the convoy-electron peak. Convoy electrons are fast electrons that leave the solid surface with about the same velocity as the projectile ion. They give rise to a cusp shaped kinematic peak and are related to the attractive Coulomb potential of positive ions. This peak was first measured in ion/atom collisions experiments [1] and shortly after for ion-solid interactions [2]. In both cases convoy electrons are produced by electron capture (ECC) [3] and by electron loss to continuum states of the projectile (ELC) [4,5]. In dense matter, these electrons are subject to a random walk under the influence of the target constituents and the projectile potential [6].Convoy electrons can be accelerated by the imagepotential of the projectile charge, as has been found for ions under glancing-angle scattering conditions at semiconductor and metal targets [7][8][9] and at normal-incidence conditions for highly charged ions at a proton-equivalent energy of 5 MeV͞u [10]. In ion-insulator interactions ionizing collisions result in a positive nuclear-track potential, which can decelerate target Auger-electrons emitted from the insulator surface [11] and accelerate desorbed positive hydrogen ions [12]. In this Letter we present first evidence for a deceleration of convoy electrons induced by 5 MeV͞u highly charged ions traversing insulating polypropylene ͓͑C 3 H 6 ͔ n ͒ foils at normal incidence.A detailed description of the experimental setup has been published previously [10,11]. 5 MeV͞u heavy ions were delivered by the heavy-ion cyclotron of the Ionenstrahl-Labor (ISL) at the Hahn-Meitner Institut. The beam was sent through a post-cyclotron stripper foil and a magnet to select projectiles with a charge-state close to equilibrium. The beam of 0.1 to 10 particle nA was collimated to about 1 mm 2 at the center of the magnetically shielded target chamber with a vacuum of typically 10 26 mbar. During the experiments the targets were wobbled in both directions perpendicular to the beam for an accurate fluence determination and for a reduction of the heat load. For the measurement of convoy-electron spectra an electrostatic zero-degree tandem spectrometer (energy resolution DE͞E 0.6% and solid angle DV 2 3 10 25 sr) was used [13]. The ions pass the first stage of the spectrometer and electrons emitted in t...