In this paper, a new approach is proposed to identify sectional deformation modes of the doubly symmetric thin-walled cross-section, which are to be employed in formulating a one-dimensional model of thin-walled structures. The approach considers the three-dimensional displacement field of the structure as the linear superposition of a set of sectional deformation modes. To retrieve these modes, the modal analysis of a thin-walled structure is carried out based on shell/plate theory, with the shell-like deformation shapes extracted. The components of classical modes are removed from these shapes based on a novel criterion, with residual deformation shapes left. By introducing benchmark points, these shapes are further classified into several deformation patterns, and within each pattern, higher-order deformation modes are derived by removing the components of identified ones. Considering the doubly symmetric cross-section, these modes are approximated with shape functions applying the interpolation method. The identified modes are finally used to deduce the governing equations of the thin-walled structure, applying Hamilton’s principle. Numerical examples are also presented to validate the accuracy and efficiency of the new model in reproducing three-dimensional behaviors of thin-walled structures.