The existence of contextuality in quantum mechanics is a fundamental departure from the classical description of the world. Currently, the quest to identify scenarios which cannot be more contextual than quantum theory is at the forefront of research in quantum contextuality. In this work, we experimentally test two inequalities, which are capable of revealing fully contextual quantum correlations, on a Hilbert space of dimension eight and four respectively, on an NMR quantum information processor. The projectors associated with the contextuality inequalities are first reformulated in terms of Pauli operators, which can be determined in an NMR experiment. We also analyze the behavior of each inequality under rotation of the underlying quantum state, which unitarily transforms it to another pure state.