This
paper discussed the selection of functional monomers and optimal
synthesis conditions for hyperbranched copolymer named as HVR, a novel
polymer flooding chemical, intended to enhance offshore heavy oil
recovery. The potential application of HVR as a polymer for oil displacement
was also evaluated. Through experiments and molecular simulations,
functional monomers AOS and OP-10 for Bohai heavy oil were screened
out due to their high viscosity reduction rates for oil, both above
90%. Moreover, the interaction energy calculation results suggested
that AOS and OP-10 were more likely to spontaneously disperse asphaltene
aggregation. Furthermore, the influence of various factors on the
synthesis of HVR was discussed using orthogonal design, and optimal
synthesis conditions were determined. The optimal conditions for HVR
synthesis are as follows: polymerization concentration of 30 wt %,
initiator dosage of 1 wt %, initiation temperature of 50 °C,
and system pH of 7; the sum of OP-10 and AOS accounts for 29.9 wt
%, with a molar ratio of 1:1; the total amount of AM and AA accounts
for 79.9 wt %, with a mole ratio of 6.5:3.5; and 3.0 G PAMAM accounts
for 0.2 wt %. Moreover, HVR demonstrated good mobility control capacity
and improved the recovery of heavy oil significantly in core flooding
tests. Injecting a slug of 0.3 PV of HVR led to the additional recovery
of 21.96 and 16.04% for oil viscosities of 350 and 500 cP, respectively.
Notably, HVR’s additional recovery was over 7% higher than
that of conventional hydrophobically associating polymer. These findings
highlight the potential of HVR as a novel polymer to enhance the heavy
oil recovery.