Cocombustion of bituminous coal (HC) and Pinus sawdust
(PS) was
investigated in this paper with the aim of determining the kinetic
parameters relevant to cocombustion reactions of their fuel blends.
PS was used because it is a waste biomass product capable of generating
energy. Motivated by the need to partly substitute HC used in existing
boilers with PS, the optimum kinetic parameters at different blending
ratios were thus investigated with the ultimate goal of diversifying
the energy portfolio for these boilers. Blended samples were prepared
with a PS substitution by mass ranging from 0 to 30%, thus producing
five samples, namely:100HC, 90HC10PS, 80HC20PS, 70HC30PS, and 100PS.
A simultaneous thermogravimetric analyzer was used to investigate
the degradation of the fuel samples under a synthetic air atmosphere
using 5, 12.5, and 20 °C/min heating rates. The kinetic parameters
were evaluated using the distributed activation energy model (DAEM)
due to its ability to evaluate complex parallel chemical mechanisms.
The influential homogenous volatile combustion and heterogenous combustion
stages produced an increasing trend for activation energy (
E
a
) with increased PS (100HC to 70HC30PS) from
an average of 61.80–104.34 kJ/mol while the pre-exponential
factor increased from 1.31 × 10
5
to 6.52 × 10
8
. Generally, blending of HC with PS did not produce a linear
variation of the kinetic parameters; thus, by using various plots,
an optimum blending ratio of 80HC20PS was deduced.