The
greatest source of loss in conventional single-junction photovoltaic
cells is their inefficient utilization of the energy contained in
the full spectrum of sunlight. To overcome this deficiency, we propose
a multijunction system that laterally splits the solar spectrum onto
a planar array of single-junction cells with different band gaps.
As a first demonstration, we designed, fabricated, and characterized
dispersive diffractive optics that spatially separated the visible
(360–760 nm) and near-infrared (760–1100 nm) bands of
sunlight in the far field. Inverse electromagnetic design was used
to optimize the surface texture of the thin diffractive phase element.
An optimized thin film fabricated by femtosecond two-photon absorption
3D direct laser writing shows an average splitting ratio of 69.5%
between the visible and near-infrared light over the 380–970
nm range at normal incidence. The splitting efficiency is predicted
to be 80.4% assuming a structure without fabrication errors. Spectral-splitting
action is observed within an angular range of ±1° from normal
incidence. Further design optimization and fabrication improvements
can increase the splitting efficiency under direct sunlight, increase
the tolerance to angular errors, allow for a more compact geometry,
and ultimately incorporate a greater number of photovoltaic band gaps.