Exposure of thermoplastics to methanol–gasoline blends: A material compatibility study

Abstract

Alcohols are increasingly being looked upon as the most viable alternative to the conventional sources of energy. Methanol is the first member of the alcohol family and can be easily synthesized from syngas. It is an attractive blend to gasoline due to its advantageous properties. There is a necessity to make sure that the infrastructure is ready to adapt these alternative fuels. Hence, the aim of this study is to assess the degradation of widely used thermoplastics in fuel tanks, pipes, and the fuel injection system, namely, polytetrafluoroethylene (PTFE), polyethyleneterephthalate (PET), and high density polyethylene (HDPE) post exposure to methanol–gasoline blends (P100, M15, and M30) for a period of 4, 10, and 30 days. The effects of the exposure were examined by comparing changes in gain/loss of mass, hardness, elongation, and tensile strength. The surface morphology changes of the polymeric coupons were characterized by scanning electron microscopy and their elemental analysis was done by energy dispersive X-ray spectroscopy. The studied materials were found to gain mass in the order HDPE > PTFE >PET. The decrease in hardness was found to be more in HDPE followed by PTFE and PET. PTFE and PET showed reduction in strength but an increase in tensile strength was observed for HDPE post exposure to fuel blend. Highest change in elongation was found in HDPE followed by PTFE and PET. The changes were found to be the least in P100 followed by M15 and maximum in M30 blends for all immersion periods.