Abstract. The inspection sensitivity of a patterned extreme ultraviolet mask with B 4 C-capped multilayer (ML) was investigated using a simulated projection electron microscope (PEM) image. Extrusion and intrusion defects with 16-nm size were detected with their intensity of >10 times the standard deviation of the background level on a half-pitch 64-nm line-and-space pattern. The defect detection sensitivity in this case was higher than that of a Ru-capped ML sample and has a potential to meet the requirement for beyond 16-nm node generation from the standpoint of patterned mask inspection using the PEM technique. These results indicate that the B 4 C capping layer, besides its good durability, has an advantage for high sensitivity of patterned mask inspection. The optimal condition of the incident beam energy was found to be 500 and 1,000 eV for the samples of B 4 C-capped ML and B 4 C-buffered Ru-capped ML, respectively. The sensitivity of defect detection was strongly affected by the difference of secondary electron emission coefficients (SEECs) between the absorber layer and capping layer. However, the small incident beam energy was found to be preferable when the SEEC difference was relatively high. © The Authors. Published by SPIE under a Creative Commons Attribution 3.0 Unported License. Distribution or reproduction of this work in whole or in part requires full attribution of the original publication, including its DOI.