NiTi shape-memory
alloy foams have attracted much attention due to their unique superelasticity,
excellent mechanical properties, and damping capacities, but their
high-temperature damping capacity and compressive strength remain
to be a challenge. Herein, we demonstrate the preparation of Ti3Sn–NiTi syntactic foams using Ti58Ni34Sn8 alloy and alumina microspheres by novel pressure
melt infiltration and air-cooling strategies. The syntactic foams
with 45% porosity contain spherical and well-distributed pores of
average size 500–600 μm. A fine lamellar Ti3Sn/NiTi eutectic with an interspacing distance of 600–900
nm and a Ti2Ni interfacial layer of 10 μm thickness
were formed between the alumina microspheres and the matrix. The syntactic
foams achieved a high specific compressive strength (110.2–110.8
MPa cm3/g) at a wide temperature range because of the large
interfacial area and good lattice strain matching in the lamellar
Ti3Sn/NiTi. They also exhibited 2% recoverable strain and
high specific energy absorption capacity (31.5 kJ/kg). Moreover, the
foams showed ultrahigh damping capacity (0.066) at a temperature range
of −150 to 200 °C. Most interestingly, the Ti3Sn–NiTi syntactic foams showed the highest comprehensive coefficient,
(σ/ρ)·tan δ, of 5.07 to date. Because
of these impressive features, Ti3Sn–NiTi syntactic
foams become a promising material for energy absorption and damping
applications.