Fabrication of a highly efficient solid state electrochemiluminescence sensor using Ru(bpy)32+ incorporated nanoZnO-MWCNTs-Nafion composite film

A novel molecularly imprinted electrochemiluminescence sensor based on a Ru(bpy)32+/MWCNTs/nano-TiO2-Nafion electrode for the detection of bisphenol A

“…-Naon based ECL system, nanohybrids with the integrated properties of two nanocomponents, such as nano-ZnO/MWCNTs, 13 nano-SiO 2 / MWCNTs 18 and Au NPs/MWCNTs, 19 have been used for the fabrication of Ru(bpy) 3…”

“…Naon is a sulfonated ion-exchange polymer which exhibits high chemical, electrochemical and thermal stabilities and good biocompatibility. 13 Naon is oen employed for the immobilization of Ru(bpy) 3 2+ due to its high ion-exchange selectivity coefficient towards Ru(bpy) 3 2+ . But the rate of charge transfer of Ru(bpy) 3 2+ in the pure Naon lm is quite low.…”

“…Also, it has been reported that the immobilized Ru(bpy) 3 2+ can migrate into the electrochemically inactive hydrophobic region of Naon over the course of time and consequently its electrochemical signal is not stable. 13 Thus, there is a great interest to overcome the mentioned problems by introducing new approaches. A variety of new nanomaterials with unique characteristics, such as multi-walled carbon nanotubes (MWCNTs), 14 graphene, 15 nano-silica (nano-SiO 2 ) 16 and nano-titanium dioxide (nano-TiO 2 ), 17 have been introduced into the Naon lm in order to improve the electrochemical and ECL properties of Ru(bpy) 3…”

A novel molecularly imprinted electrochemiluminescence sensor based on cobalt nitride nanoarray electrode for the sensitive detection of bisphenol S

“… 14 However, the modified electrode conductivity is easily affected by the Nafion membrane. 15 For obtaining the highest ECL signals and thus reducing the background noise, it is important to load as much amount of Ru(bpy) 3 2+ as possible onto the electrode; it is thus expected that a powerful approach has to be introduced to address the problems.…”

Luminol‐Pendant Chemiluminescent Polymethacrylamide‐Based Polymers for Peroxide Sensing in Live Cell Imaging.

“…Other luminophores like Ru(bpy) 3 2+ were also immobilized in a cationic exchange polymers such as Nafion or adsorption on electrochemically oxidized graphite in screen printed cells for ECL studies . But simple immobilization of luminol over resins often results in poor adsorption causing the leakage of luminol.…”