Emerging concept of "nanoarchitectonics" has been proposed as a way to apply the progress of nanotechnology to materials science. In the introductory parts, we briefly explain the progress in understanding materials through nanotechnology, the overview of nanoarchitectonics, the effects of nanoarchitectonics on the development of functional materials and devices, and outline of nanoarchitectonics intelligence as a main subject of this review paper. In the following sections, we explain the process of constructing intelligent devices based on atomic switches, in which the behavior of atoms determines the device functions, by integrating them with nanoarchitectonics. The contents are categorized into (i) basic operation of atomic switch, (ii) artificial synapse, (iii) neuromorphic network system, (iv) hetero-signal conversion, (v) decision making device, and (vi) atomic switch in practical uses. The atomic switches were originally relatively simple ON/OFF binary-type electrical devices, but their potential as multi-level resistive memory devices for artificial synapses and neuromorphic applications