Due to the advantages of relatively low cost, increased energy efficiency, increased deposition rate, and the capacity to create medium to large scale components, wire + arc additive manufacturing (WAAM) has gained growing interest. Super martensitic stainless steel (SMSS) combines outstanding strength, ductility, and corrosion resistance, making it a great option for WAAM. In the present work, an SMSS component was successfully produced by WAAM. Additionally, the influence of post-manufactured heat treatment on the microstructural characteristics and mechanical properties of SMSS components was systematically examined. A microstructural analysis of the as-printed and heat-treated samples revealed the formation of typical martensite and a small amount of retained austenite. However, the sample heat-treated by solutionizing at 1050 °C for 1 h followed by aging at 400 °C for 2 h exhibited a finer martensitic structure with an effective grain size of 5.6 μm compared to as-printed sample, leading to an increase in ultimate tensile strength from 1054 ± 6 MPa to 1141 ± 3 MPa with a concomitant increase in elongation from 7.8 ± 0.4% to 12.6 ± 0.2%. Additionally, the fracture morphology of the solution + aging sample demonstrated a more uniform distribution and greater mean size of dimples, indicating better ductility.