2011
DOI: 10.1021/am200519w
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Field Emission Properties of Low-Temperature, Hydrothermally Grown Tungsten Oxide

Abstract: Tungsten oxide layers have been prepared on conductive glass substrates using aqueous chemical growth from a sodium tungstate precursor at low-temperature hydrothermal conditions. The deposits were then tested as cold electron emitters. Traceable layers could be deposited only within a narrow pH range of 1.5À2 at a time length not exceeding 4 h. Transmittance in the visible spectrum was found to decrease with deposition time. The presence of both monoclinic and hexagonal phases was always detected. At the long… Show more

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Cited by 35 publications
(14 citation statements)
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“…The peaks at 702 and 428 cm −1 are blue-shifted, indic The oxygen O 1s spectrum can be deconvoluted into two peaks, as shown in Figure 6b. Peak at 530.5 eV, attributing 26% to the O 1s photoelectrons, corresponds to O 2− bonded to W 6+ in WO 3 [26]. Peak at 532.3 eV may correspond to oxygen O 2− bonded to SiO 2 (substrate), C-O bonds or lower oxidation states of O in W-O bonds.…”
Section: Raman Spectroscopymentioning
confidence: 99%
“…The peaks at 702 and 428 cm −1 are blue-shifted, indic The oxygen O 1s spectrum can be deconvoluted into two peaks, as shown in Figure 6b. Peak at 530.5 eV, attributing 26% to the O 1s photoelectrons, corresponds to O 2− bonded to W 6+ in WO 3 [26]. Peak at 532.3 eV may correspond to oxygen O 2− bonded to SiO 2 (substrate), C-O bonds or lower oxidation states of O in W-O bonds.…”
Section: Raman Spectroscopymentioning
confidence: 99%
“…At these tips, the electric field rises from EE2.5 Â 10 5 V/cm to E$ 10 7 V/cm. Therefore a layer of tungsten oxides might be a source of high field-emission electron current [21][22][23]. This stimulates the glow discharge generation and production of radicals and ions in the vicinity of the wire surface.…”
Section: Etching Processmentioning
confidence: 99%
“…Nanoparticles synthesis with unique properties is a new area of research which is a great importance. There are various methods to synthesize these materials in liquid phase such as hydrothermal [15][16][17][18] , sol-gel [19][20][21][22] , micro emulsion and microbial processes, out of these methods sol gel is a simple and cost effective method 23 . Due to different…”
Section: Introductionmentioning
confidence: 99%