2008
DOI: 10.3144/expresspolymlett.2008.82
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Field strength dependence of the high-frequency viscoelastic relaxation process in polyaniline/silicone oil electrorheological suspensions

Abstract: Abstract. Polyaniline (PANI) was synthesized via oxidative coupling polymerization in acid conditions and de-doped in ammonia solution. The electrorheological (ER) properties of the PANI/silicone oil suspensions were investigated in the oscillatory mode shear, with particular focus on the high frequency region, where a crossover in G′(ω) and G″(ω) signals the onset of a dissipative relaxation process, presumed to be associated with motion of PANI particles within the fibrillar structures generated by the elect… Show more

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