The electro-optic (EO) coefficients r 22 of a congruent LiTaO 3 bulk crystal, with dimensions of 6 × 5 × 20 mm 3 ,havebeen measured over a wide frequency range (from dc up to 150 MHz) using the novel and elaborate step-voltage time-response method (TRM). At low frequencies, these results are compared with those obtained with the frequency-doubling EO-modulation (FDEOM) method. From these measurements, the clamped and unclamped EO coefficients, r S ,respectively, have been derived and the acoustic contribution r a 22 to the EO effect has been deduced and compared with theoretically calculated values. Also, using the values of acoustic contribution, r a ,thetrue value of the EO coefficient r 22 has been extracted. Lastly, the above results are compared with those obtained for a pure congruent LiNbO 3 crystal in the framework of a typical intensity-modulation (IM) EO system.