Spatial quantum optics based on the high-order transverse mode is important for the super-resolution measurement and quantum image beyond the shot noise level. Quantum entanglement of the transverse plane Hermite-Gauss TEM 01 mode has been demonstrated experimentally in this paper. Two squeezed TEM 01 modes, which are generated by a pair of degenerate optical parametric amplifiers (DOPA) with the nonlinear crystals of periodically poled KTiOPO 4 , have been combined to produce TEM 01 mode entanglement using a beam splitter. The 1.5 dB for the sum of amplitude and 1.2 dB for the difference of phase below shot-noise level is achieved with the measurement system of a Bell state detection.