Gibbs free energy of formation of Bi2O3 from EMF cells with δ-Bi2O3 solid electrolyte

Cahen, H.T.; Verkerk, M.J.; Broers, G.H.J.

doi:10.1016/0013-4686(78)87011-x

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1978

2021

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Cited by 10 publications

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“…As solid electrolytes CSZ (calcia stabilized zirconia) [9,10] and 6-Bi203 [11] have been used. In the former cases [9,10] no attention was paid by the authors to problems which can arise by reaction between the Bi2Oa and the CSZ.…”

Section: Introductionmentioning

confidence: 99%

Free energy of formation of stabilized Bi2O3 (fcc) from e.m.f. measurements

Verkerk

Burggraaf

1980

J Appl Electrochem

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Using cells with calcia stabilized zirconia as the solid electrolyte, the standard free energy of formation of stabilized Bi203 (fcc) was determined in the temperature range 750-950 K. The stability against reduction of stabilized Bi:O3 (fcc) is not increased with respect to pure 6-Bi203 (fcc). The corrosion of the calcia stabilized zirconia tube caused by Bi203 which took place along the grain boundaries, was investigated.

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