2011
DOI: 10.1039/c0gc00395f
|View full text |Cite
|
Sign up to set email alerts
|

Glycerol eutectics as sustainable solvent systems

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
2

Citation Types

29
553
4
16

Year Published

2012
2012
2022
2022

Publication Types

Select...
5
2

Relationship

0
7

Authors

Journals

citations
Cited by 712 publications
(602 citation statements)
references
References 28 publications
29
553
4
16
Order By: Relevance
“…In this work, if the molar ratio of salt to acid decrease thus the hydrogen bonding ability also increased and thus leading to increase in the polarity (or decrease in polarity scale). Similar result also reported by Abbot et al [14] that the polarity scale E T (30) (using Reichardt's dye) of choline chloride-glycerol DES decrease with an increase in glycerol concentration. The viscosity of betaine monohydrate-carboxylic acid mixtures in the range of 6.4-73 cSt at a temperature of 40°C (Figure 1b).…”
Section: Resultssupporting
confidence: 79%
See 1 more Smart Citation
“…In this work, if the molar ratio of salt to acid decrease thus the hydrogen bonding ability also increased and thus leading to increase in the polarity (or decrease in polarity scale). Similar result also reported by Abbot et al [14] that the polarity scale E T (30) (using Reichardt's dye) of choline chloride-glycerol DES decrease with an increase in glycerol concentration. The viscosity of betaine monohydrate-carboxylic acid mixtures in the range of 6.4-73 cSt at a temperature of 40°C (Figure 1b).…”
Section: Resultssupporting
confidence: 79%
“…However, viscosity of the mixture tends to similar with decrease in the mole ratio of salt to acid. The high viscosity of DES is often attributed to the presence of an extensive hydrogen bond network between salt and hydrogen bond donor which causing the lack of free volume within the DES [14]. The betaine monohydrate-propionic acid mixture has greater stability than betaine monohydrate-acetic acid mixture at the eutectic composition [10].…”
Section: Resultsmentioning
confidence: 99%
“…7 A DES is defined as a mixture of hydrogen bond donor (HBD) systems with simple halide salts which produce liquids. 8 Their physicochemical properties resemble those of ionic liquids. Abbott's fundamental work inspired other researchers to exploit the unusual properties of this system.…”
Section: Carolin Rußmentioning
confidence: 99%
“…In the last few years, different (uncharged) hydrogen bond donors of natural and synthetic origin were used in combination with choline chloride. [8][9][10][11][12] As in the case of ILs, the melting point of the mixtures is not predictable, but some general trends can be derived. Abbott hypothesised that the melting point depression is caused by charge delocalisation due to hydrogen bonding between the halide anion and the hydrogen bond donor.…”
Section: Carolin Rußmentioning
confidence: 99%
See 1 more Smart Citation