Recent trends in consumer electronics have led to a proliferation of high dynamic range (HDR) video acquisition and transmission studies. High-end video capturing systems increase the bit depth of each pixel to adapt to the high-contrast ambient light. However, the extended bit depth is pathetically meager compared with the far wider dynamic range of the incident light. What's more, incompatibility issues for the subsequent compression and transmission system may be arisen along with the increased bit depth. In this paper, we propose an auto complementary exposure (ACE) algorithm for optimal exposure parameter estimation under Siamese Trigger (ST) mode to maximize the entropy of the output HDR image. With the proposed algorithm, neither the sensor nor other related hardware needs to be modified. Only the auto-exposure algorithm in the firmware needs to be updated. In the proposed ACE algorithm, every two consecutive images are treated as Siamese twins, and the exposure parameters for the twin images are calculated simultaneously. The target of the ACE algorithm is not to maximize the entropy of each image but to maximize that of the fused image. Compared to existing auto exposure or bracketed fusing algorithms, the proposed algorithm has three significant advantages. Firstly, no extra bit-depth is needed to embrace the details of the scene. Thus the image transmission system is not affected. Secondly, only two raw images are necessary for one output fused HDR image. The computation load is relatively low. Thirdly, the proposed method can fit video recording, which has a broader application prospect than HDR image capturing. Experiment results on a self-built database and publicly accessible database demonstrate that the algorithm works well under various types of scenarios. Furthermore, the experiment results on the real-time system show that the captured video image reveals many details under high dynamic scenes.