We compare two quantities to describe a microstructure: the length fraction of normalΣ3/normalΣ9‐grain boundaries and the number fraction of normalΣ3‐x‐x/normalΣ3‐normalΣ3‐normalΣ9‐triple junctions using Cu, Ni and four of their alloys in several microstructural states. The fractions of normalΣ3‐grain boundaries show similar tendencies as the respective fractions of normalΣ3‐x‐x‐triple junctions in relation to the grain size upon deformation and annealing. However, the fraction of normalΣ9‐grain boundaries stagnates at certain grain sizes, while there is still a considerable change of normalΣ3‐normalΣ3‐normalΣ9‐triple junctions during grain growth, meaning that the normalΣ3‐normalΣ3‐normalΣ9‐triple junction microstructure is still evolving. To analyze the evolution of the triple junction microstructure, a program, such as pythorient, is necessary.