2022
DOI: 10.1039/d2cy01709a
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Graphite carbon ring modified carbon nitride with a strong built-in electric field for high photocatalysis-self-Fenton performance

Abstract: The photocatalysis-self-Fenton is a novel technology for high-fluent degradation and high mineralization of aqueous organic pollutants. Herein, we constructed a novel photocatalysis-self-Fenton system in which graphite carbon (Cg) rings-doped graphitic...

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Cited by 20 publications
(5 citation statements)
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“…In addition, the utilization efficiencies of H 2 O 2 ( • OH transformation efficiencies) of different systems were calculated, and the related results were provided in Figure 3f. The • OH transformation efficiency of the photo-self-Fenton reached 34.3%, approximately 1.52 and 6.13 times compared with that of the photo-Fenton and Fenton system, respectively, which may be intrinsic to the higher degradation efficiency of the photo-self-Fenton system [44,45]. Apparently, the degradation efficiency of the photo-self-Fenton system based on RF originated from the in situ efficient production and superior utilization efficiency of H 2 O 2 .…”
Section: Resultsmentioning
confidence: 95%
“…In addition, the utilization efficiencies of H 2 O 2 ( • OH transformation efficiencies) of different systems were calculated, and the related results were provided in Figure 3f. The • OH transformation efficiency of the photo-self-Fenton reached 34.3%, approximately 1.52 and 6.13 times compared with that of the photo-Fenton and Fenton system, respectively, which may be intrinsic to the higher degradation efficiency of the photo-self-Fenton system [44,45]. Apparently, the degradation efficiency of the photo-self-Fenton system based on RF originated from the in situ efficient production and superior utilization efficiency of H 2 O 2 .…”
Section: Resultsmentioning
confidence: 95%
“…The photogenerated holes in the VB are responsible for oxidizing organic toxic dye molecules into smaller fragments and eventually mineralizing them at the end. 52 The ˙OH radicals are formed due to the participation of water. Furthermore, the photogenerated electrons in the CB interact with H 2 O 2 to form a large number of ˙OH radicals.…”
Section: Resultsmentioning
confidence: 99%
“…This can be attributed to the efficient Fe 3+ reduction by photogenerated electrons, ensuring sustainedly high H 2 O 2 utilization and continuous • OH formation. [ 59 ] As shown in Figure 6b, traditional Fenton degradation nearly ceased within the initial 40 min of the process since most added H 2 O 2 rapidly converted to • OH and recombined with each other instead of reacting with MTZ. [ 60 ] As summarized in Table S4 (Supporting Information), the photocatalysis‐self‐Fenton reaction with C≡N─CN/IS/6%Ppy achieved higher removal rate and lower H 2 O 2 usage when compared to previous materials and methods.…”
Section: Resultsmentioning
confidence: 99%