Growth of 2D black phosphorus film from chemical vapor deposition

Smith, Joshua B.; Hagaman, Daniel; Ji, Hai‐Feng

doi:10.1088/0957-4484/27/21/215602

Cited by 315 publications

(231 citation statements)

References 40 publications

(50 reference statements)

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“…These large‐scale BP films are as thin as 2 nm but the quality is quite compromised by the amorphous feature. Some scientists turned to the traditional high‐pressure or CVT method to produce BP thin films in large scale by controlling the reaction time . By evaporating the RP powders at 400 °C followed by the condensation to a flexible substrate, RP thin films with controllable thickness can be formed; these RP thin films can then be converted to BP thin films at high pressure (10 GPa) and room temperature.…”

Section: From Bulk To 2dmentioning

confidence: 99%

Optical and Optoelectronic Properties of Black Phosphorus and Recent Photonic and Optoelectronic Applications

Sun

et al. 2019

Small Methods

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The rapid development of the semiconductor industry calls for the exploration of novel semiconductors to cater to modern technical and commercial needs. Recently, black phosphorus (BP) has emerged as a new class of 2D semiconducting material and has attracted intensive research attention. The high carrier mobility and tunable direct bandgap of BP deliver great promise in photonic and optoelectronic device applications. Furthermore, the unique intrinsic anisotropy arising from the puckered structure can be exploited in the design of new devices. This review briefly introduces the history of BP and puts emphasis on recent advances pertaining to its optical properties and applications in the photonic and optoelectronic fields. From the perspective of mass production and practical use of BP, some of the research challenges and opportunities are discussed.

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Section: From Bulk To 2dmentioning

confidence: 99%

Optical and Optoelectronic Properties of Black Phosphorus and Recent Photonic and Optoelectronic Applications

Sun

et al. 2019

Small Methods

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“…Interestingly, after further passivation using Al 2 O 3 , their sample with the P x O y layer showed outstanding stability (at least 30 d) under ambient conditions (see Figure 1e). [1] Recently, Smith et al [34] reported an in situ CVD method to grow large-area 2D BP directly on a silicon substrate from red phosphorus. These van der Waals heterostructures not only show improved stability but also exhibit unique properties, including high carrier mobility and hybrid functionalities.…”

Section: Introductionmentioning

confidence: 99%

Black Phosphorus: Synthesis and Application for Solar Cells

Batmunkh

Bat‐Erdene

Shapter

2017

Advanced Energy Materials

134

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methods suffer from several limitations. Even though many efforts focused on the synthesis of BP derivatives have been reported, [10] research into the synthesis, properties, and applications of BP derivatives is still at an early stage, and a lot remains to be investigated.Although this research field is only a few years old, BP derivatives have already been utilized in a wide range of device applications such as transistors, batteries, supercapacitors, and solar cells. [20][21][22][23] These recent advancements highlight the potential importance of these exciting materials. In particular, based on recent theoretical and experimental studies, BP derivatives have shown great promise in enhancing the performance and lowering the cost of emerging photovoltaics (PVs). Considering the rapid advances of this cutting-edge research area, highlighting these discoveries and findings of the past few years is of great importance.Herein, we focus on providing a concise overview and timely update on the synthesis of BP derivatives and their recent applications in emerging solar cells including organic PV (OPV), dye-sensitized solar cells (DSSCs), heterojunction solar cells (HJSCs), and perovskite solar cells (PSCs).

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“…Chemical vapor deposition (CVD) methods that have been very successfully employed in the production of graphene24a and other 2D materials like boron nitride77 would be highly desirable. However, a first attempt in this direction using the conversion of red phosphorus into the thermodynamically more stable BP was reported 78. Beside establishing procedures for the so far elusive CVD approach, possible concepts for large‐area production of SL‐BP could involve the oxidation of surface‐supported reduced SL‐BP n − generated from the Coulomb‐force‐driven exfoliation and deposition of AM‐BPICs (AM=alkali metal, BPIC=BP intercalation compound).…”

Section: The Advent Of the Black Phosphorus Chemistrymentioning

confidence: 99%

Post‐Graphene 2D Chemistry: The Emerging Field of Molybdenum Disulfide and Black Phosphorus Functionalization

2018

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The current state of the chemical functionalization of three types of single sheet 2D materials, namely, graphene, molybdenum disulfide (MoS2), and black phosphorus (BP) is summarized. Such 2D sheet polymers are currently an emerging field at the interface of synthetic chemistry, physics, and materials science. Both covalent and non‐covalent functionalization of sheet architectures allows a systematic modification of their properties, that is, an improvement of solubility and processability, the prevention of re‐aggregation, or band‐gap tuning. Next to successful functionalization concepts, fundamental challenges are also addressed. These include the insolubility and polydispersity of most 2D sheet polymers, the development of suitable characterization tools, the identification of effective binding strategies, the chemical activation of the usually rather unreactive basal planes for covalent addend binding, and the regioselectivity of plane addition reactions. Although a number of these questions remain elusive in this Review, the first promising concepts to overcome such hurdles are presented.

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Growth of 2D black phosphorus film from chemical vapor deposition

Cited by 315 publications

References 40 publications

Optical and Optoelectronic Properties of Black Phosphorus and Recent Photonic and Optoelectronic Applications

Optical and Optoelectronic Properties of Black Phosphorus and Recent Photonic and Optoelectronic Applications

Black Phosphorus: Synthesis and Application for Solar Cells

Post‐Graphene 2D Chemistry: The Emerging Field of Molybdenum Disulfide and Black Phosphorus Functionalization

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