Growth of Bi2ZnOB2O6 crystal by the Czochralski method

Li, Feng; Pan, Shilie; Hou, Xueling; Zhou, Zhongxiang

doi:10.1016/j.jcrysgro.2010.03.004

Cited by 17 publications

(5 citation statements)

References 23 publications

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“…Very recently, our group has grown large BZB crystal with high optical quality. The formula of Bi 2 ZnB 2 O 7 has been changed to Bi 2 ZnOB 2 O 6 according to its anionic structure. − Preliminary investigations of BZB indicate that it is a promising NLO material with large second-harmonic generation (SHG) response (3–4 KH 2 PO 4 (KDP)), wide optical transmission range, and congruent melting property. − Considering these excellent properties of BZB, it is interesting and meaningful to grow a large single crystal and further investigate its structure–property relationship. A few theoretical studies of BZB have been published.…”

Section: Introductionmentioning

confidence: 99%

Experimental and Theoretical Studies on the Linear and Nonlinear Optical Properties of Bi₂ZnOB₂O₆

Su¹,

Wang

Yang³

et al. 2013

J. Phys. Chem. C

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A large single crystal of a nonlinear optical material Bi2ZnOB2O6 (BZB) has been grown by the Czochralski method. The experiments of linear and nonlinear optical property were performed. On the basis of the density functional theory (DFT), the first-principles calculations have been employed to study the structural and electronic properties of BZB successfully. The calculated results are essentially consistent with the corresponding experimental results. In addition, to gain further insight into the structure–property relationship, a real-space atom-cutting method was adopted to analyze the origin of the nonlinear optical response of BZB for the first time. The results indicate that the contributions of the (BiO6)9– and (B2O5)4– groups are dominant in the BZB crystal for producing large microscopic second-order susceptibilities.

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Section: Introductionmentioning

confidence: 99%

Experimental and Theoretical Studies on the Linear and Nonlinear Optical Properties of Bi₂ZnOB₂O₆

Su¹,

Wang

Yang³

et al. 2013

J. Phys. Chem. C

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“…Sizable single crystals of BZB were grown recently [2][3][4][5]. BZB melts congruently and can be grown easily.…”

Section: Introductionmentioning

confidence: 99%

Crystal growth and nonlinear optical coefficients of Bi2ZnOB2O6

Li¹,

Pan²

2011

Journal of Crystal Growth

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“…Reprinted with permission from Ref. [83,152], Copyright (2009) American Chemical Society, Copyright (2010) Elsevier, respectively.…”

Section: Figurementioning

confidence: 99%

Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

et al. 2019

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Borates have been regarded as a rich source of functional materials due to their diverse structures and wide applications. Therein, zincobrates have aroused intensive interest owing to the effective structural and functional regulation effects of the strong-bonded zinc cations. In recent decades, numerous zincoborates with special crystal structures were obtained, such as Cs3Zn6B9O21 and AZn2BO3X2 (A = Na, K, Rb, NH4; X = Cl, Br) series with KBe2BO3F2-type layered structures were designed via substituting Be with Zn atoms, providing a feasible strategy to design promising non-linear optical materials; KZnB3O6 and Ba4Na2Zn4(B3O6)2(B12O24) with novel edge-sharing [BO4]5− tetrahedra were obtained under atmospheric pressure conditions, indicating that extreme conditions such as high pressure are not essential to obtain edge-sharing [BO4]5−-containing borates; Ba4K2Zn5(B3O6)3(B9O19) and Ba2KZn3(B3O6)(B6O13) comprise two kinds of isolated polyborate anionic groups in one borate structure, which is rarely found in borates. Besides, many zincoborates emerged with particular physicochemical properties; for instance, Bi2ZnOB2O6 and BaZnBO3F are promising non-linear optical (NLO) materials; Zn4B6O13 and KZnB3O6 possess anomalous thermal expansion properties, etc. In this review, the synthesis, crystal structure features and properties of representative zincoborates are summarized, which could provide significant guidance for the exploration and design of new zincoborates with special structures and excellent performance.

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Growth of Bi2ZnOB2O6 crystal by the Czochralski method

Cited by 17 publications

References 23 publications

Experimental and Theoretical Studies on the Linear and Nonlinear Optical Properties of Bi₂ZnOB₂O₆

Experimental and Theoretical Studies on the Linear and Nonlinear Optical Properties of Bi₂ZnOB₂O₆

Crystal growth and nonlinear optical coefficients of Bi2ZnOB2O6

Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

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Growth of Bi2ZnOB2O6 crystal by the Czochralski method

Cited by 17 publications

References 23 publications

Experimental and Theoretical Studies on the Linear and Nonlinear Optical Properties of Bi2ZnOB2O6

Experimental and Theoretical Studies on the Linear and Nonlinear Optical Properties of Bi2ZnOB2O6

Crystal growth and nonlinear optical coefficients of Bi2ZnOB2O6

Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

Contact Info

Product

Resources

About

Experimental and Theoretical Studies on the Linear and Nonlinear Optical Properties of Bi₂ZnOB₂O₆

Experimental and Theoretical Studies on the Linear and Nonlinear Optical Properties of Bi₂ZnOB₂O₆