Triboelectric
nanogenerators (TENGs) are useful for harvesting
clean and widely distributed water droplet energy with high efficiency.
However, the commonly used polymer films in TENGs for water droplet
energy harvesting have the disadvantages of poor breathability, poor
skin affinity, and irreparable hydrophobicity, which greatly hinder
their wearable uses. Here, we report an all-fabric TENG (F-TENG),
which not only has good air permeability and hydrophobic self-repairing
properties but also shows effective energy conversion efficiency.
The hydrophobic surface composed of SiO2 nanoparticles
and poly(vinylidenefluoride-co-hexafluoropropylene)/perfluorodecyltrichlorosilane
(PVDF-HFP/FDTS) exhibits a static contact angle of 157° and displays
excellent acid and alkali resistance. Because of its low glass transition
temperature, PVDF-HFP can facilitate the movement of FDTS molecules
to the surface layer under heating conditions, realizing hydrophobic
self-repairing performance. Furthermore, with the optimized compositions
and structure, the water droplet F-TENG shows 7-fold enhancement of
output voltage compared with the conventional single-electrode mode
TENG, and a total energy conversion efficiency of 2.9% is achieved.
Therefore, the proposed F-TENG can be used in multifunctional wearable
devices for raindrop energy harvesting.