We have developed a calibration system for the Zener voltage standards using a programmable Josephson voltage standard (PJVS) for liquid-helium consumption reduction and improvement in the calibration performance. The PJVS array is composed of 524 288 niobium nitride (NbN)-based overdamped Josephson junctions and is cooled by a 10-K compact cooler. To verify the validity of the system, indirect and direct comparisons of the PJVS system and our conventional Josephson voltage standard system have been carried out. As a result, an agreement within a relative expanded uncertainty of 8.4 × 10 −10 was obtained for a nominal voltage of 10 V. We also discuss the uncertainty sources in the calibration of the Zener voltage standards using our PJVS system.Index Terms-Calibration, dc voltage, Josephson junction array, liquid helium, mechanical cooler, programmable Josephson voltage standard (PJVS), Zener voltage standard.