Reliable
and long-lasting water repellency, ideally based on fluorine-free
additives, is a desired utility in functional textiles, e.g., for
outdoor active wear, workwear, and even protective medical garments.
To date, such coating treatments have usually been accomplished by
pad-dry-cure, electrolysis, or similar methods that tend to be time-consuming
and often yield unsatisfactory coating results. In this study, hydrophobic-coated
polyester substrates were prepared using a sonochemical coating process.
Comparisons were made between the performances and associated morphological
variations of amorphous nano-dimensional silica versus nanocrystalline
cupric oxide hydrophobic coatings, which were separately made and
successfully loaded, via a random distribution, onto mesoporous polyester-woven
fabric substrates. Shorter sonication times seem to allow for retention
of preformed morphologies into the subsequent coating patterns. The
nanocomposite coatings and their components were characterized using
X-ray diffraction (XRD), attenuated total reflectance-infrared Fourier
transform infrared (ATR-FTIR), SEM, scanning electron microscope (SEM),
UV–vis, dynamic light scattering (DLS), and Raman spectroscopy
measurements. Almost all coatings displayed highly hydrophobic static
water contact angle valuesfor CuO, these values further increased
with time, a rarely reported aging effect thought due to the presence
of mixed oxides that likely formed in the coating due to the spallative
ultrasonic approach. In addition, the efficacy of these hydrophobic
semipermeable fabrics to hexane–water mixture separations,
with varying concentrations of Na2SO4, was found
to be >99% for optimized membranes, with an associated permeation
flux of ∼5.9 ± 2 L m–2 h–1, a water content of ∼0%, and a salt rejection capability
of ∼94%. Thus, non-fluorine-containing sonochemical coating
formulations and processes are ideal in the coating of soft matter,
polymeric textiles.