Heteropolymolybdates of AsIII, SbIII, BiIII, SeIV, and TeIV Functionalized by Amino Acids

Kortz, Ulrich; Savelieff, Masha G.; Ghali, Fida Y. Abou; Khalil, Lina; Maalouf, Samer A.; Sinno, Durriyah

doi:10.1002/1521-3773(20021104)41:21<4070::aid-anie4070>3.0.co;2-3

Cited by 286 publications

(109 citation statements)

References 6 publications

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“…The investigation of interactions between POMs and biomolecules in general [11] as well as between POMs and purine bases in particular are interesting for three major reasons: (1) They are interesting from the structural point of view, due to a multitude of possibilities of non-covalent interactions of the purine bases [12]; (2) The resulting hybrid organic-inorganic solids are in focus of current scientific research in order to elucidate the possibilities of a targeted design of functional materials; (3) They might shed some light onto the mechanism of the pharmacological action of polyoxoanions [9].…”

Section: Open Accessmentioning

confidence: 99%

Polyoxotungstates in Molecular Boxes of Purine Bases

Куликов

Meyer

2014

Crystals

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O) 2 (3) (GuaH = guaninium, thbH = theobrominium) were synthesized in acidified acetonitrile solutions. The polyoxotungstates in all of these compounds are surrounded by an organic matrix consisting of protonated purine bases and water molecules. The distinctive structural arrangement of the aromatic organic cations around the polyoxoanions parallel to their faces is reminiscent of nanosized boxes. The results of IR spectroscopy are consistent with previously reported results for polyoxotungstates and neat organic compounds. The polyoxoanions are reduced to tungsten(IV) oxide upon heating over 400 °C in an intramolecular redox reaction.

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Section: Open Accessmentioning

confidence: 99%

Polyoxotungstates in Molecular Boxes of Purine Bases

Куликов

Meyer

2014

Crystals

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“…Indeed, thanks to the presence of carboxyl and amino groups, these molecules can act not only as hydrogen-bonding acceptors or hydrogen-bonding donors, but also as bidentate or tridentate ligands which can coordinate to various metals [18,19]. In fact, several polymolybdates modified with amino acids and metalamino acid complexes have been reported [20][21][22][23][24][25]; in return, amino acid modified polyoxotungstates remain largely unexplored [26][27][28]. Herein, we report the synthesis and characterization of an extended structure based on paradodecatungstate clusters and sodium-aminoacetic acid complexes.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of high-dimensional structure based on paradodecatungstate clusters and sodium–aminoacetic acid complex subunits

Chaalia¹,

Ayed²,

Haddad³

2010

Struct Chem

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An organic-inorganic hybrid material based on paradodecatungstate building blocks and sodium-aminoacetic acid complex subunits,{Na 10 (H 3 N-CH 2 -COO) 2 [H 2 W 12 O 42 ]}Á28H 2 O (1), have been synthesized under mildly acidic conditions. This compound was characterized by single-crystal X-ray diffraction, elemental analysis, IR and UV-visible spectroscopies, and cyclic voltammetry. The compound crystallizes in the triclinic space group P-1 with a = 11.879 (2) Å , b = 12.706(2) Å , c = 13.067(2) Å , a = 74.11(3)°, b = 79.71(3)°, c = 65.95(3)°, V = 1727.2(5) Å 3 , and Z = 1. The crystal structure consists of infinite 2D layers constructed from [H 2 W 12 O 42 ] 10-clusters and sodium-aminoacetic acid complexes; adjacent layers are further joined by the complex units and sodium cations to yield a three-dimensional network.

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“…Also, polyoxometalates possess superacid acidity, strong oxidizability, and exhibit fast reversible multiple electron redox transformations under rather mild conditions and high stability of most of their redox states [5][6][7] which make them very useful in the preparation of modified electrodes. The hybrid materials of POMs with organic or biochemical substances can combine both inorganic and organic qualities, possessing new synergistic properties and diverse applications in photo-and electro-chromism, magnetism, catalysis and medicine [8][9][10][11][12][13][14][15][16][17]. Therefore, the design of new kinds of hybrid materials containing both POMs and organic subunits and the development of their beneficial properties can be investigated for both fundamental and applied chemistry.…”

Section: Introductionmentioning

confidence: 99%

Electrochemical behavior of an inorganic–organic hybrid based on isopolymolybdate anions and ethylenediamine

Zhang

O’Halloran

et al. 2009

J Appl Electrochem

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The one-dimensional inorganic-organic compound, (C 2 H 10 N 2 )[Mo 3 O 10 ], was synthesized hydrothermally, and characterized by single crystal X-ray diffraction. The compound was used as a bulk-modifier to fabricate a renewable three-dimensional chemically modified carbon paste electrode (Mo-CPE) by direct mixing. The electrochemical properties of (C 2 H 10 N 2 )[Mo 3 O 10 ]-modified Mo-CPE were investigated with respect to their pH-dependence, stability and electrocatalytic activity. The hybrid material bulk modified Mo-CPE not only displays good electrocatalytic activity toward the reduction of BrO 3 -, IO 3 -, NO 2 -and H 2 O 2 , but also exhibits good stability and multiple repeatability by simply polishing on the surface of a wet filter paper, a feature which is important for practical applications.

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Heteropolymolybdates of AsIII, SbIII, BiIII, SeIV, and TeIV Functionalized by Amino Acids

Cited by 286 publications

References 6 publications

Polyoxotungstates in Molecular Boxes of Purine Bases

Polyoxotungstates in Molecular Boxes of Purine Bases

Synthesis and characterization of high-dimensional structure based on paradodecatungstate clusters and sodium–aminoacetic acid complex subunits

Electrochemical behavior of an inorganic–organic hybrid based on isopolymolybdate anions and ethylenediamine

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