Hierarchical porous polymeric ionic liquids with excellent adsorption performance for phenolic compounds

Agile Construction of Porous Organic Frameworks Pending Carboxylic Acids and Imidazolium-Based Ionic Liquids for the Efficient Fixation of CO2 to Cyclic Carbonates

“…The introduction of the imidazolium-based ILs, together with the porous structure with a high surface area, the as-prepared CILs-POF m is anticipated to present satisfactory CO 2 adsorption capacity. 37,58 The results indicate that the CO 2 adsorption capacity of CILs is only 0.41 mmol g −1 and the values of the CILs-POF m are up to 1.71−2.14 mmol g −1 at 273 K and 1 atm (Figure 5 and Table 1). These values are higher than those previously reported for cross-linked ionic polymers.…”

Ionic liquids and deep eutectic solvents for the recovery of phenolic compounds: effect of ionic liquids structure and process parameters

“…Zhang et al synthesized novel polymeric ILs using imidazolium monomers. 186 The synthesized ILs have a porous structure and Lewis basic active sites which efficiently adsorbed both small and large phenolic molecules from water. The adsorption capacity of tannic acid, 4-nitrophenol, and 4-chlorophenol on the synthesized solid polymeric ILs were 911, 460, and 433 mg g −1 , respectively.…”

Enhanced fluorescence quenching forp-nitrophenol in imidazolium ionic liquids using a europium-based fluorescent probe

“…The progress in IL science inevitably means that the exposure of PNP and their derivatives is not limited to water and traditional organic solvents. For instance, the removal efficiency of PNP in wastewater has been shown to be improved signicantly using ILs, [25][26][27][28][29] and metal nanoparticles used for the catalytic reduction of nitrophenol have been shown to be stabilized and size-controlled by ILs. [30][31][32][33][34][35] Consequently, the detection of nitro compounds in ILs has become a reality, and it is thus signicant to investigate the potential inuence of ILs on the uorescence and response performance of uorescent probes.…”

“…1a): 1-butyl-3-methyl-imidazolium tetrauoroborate ([Bmim]BF 4 ), 1-hexyl-3-methyl-imidazolium bromide ([Hmim] Br), 1-butyl-3-methyl-imidazolium triuoromethansulfonate ([Bmim]TfO), 1-butyl-3-methyl-imidazolium triuoroacetate ([Bmim]TA), and 1-butyl-3-methyl-imidazolium nitrate ([Bmim] NO 3 ) to clarify the specic solvent effect on the detection performance of the europium-based uorescent probe. ILs with imidazolium as cations were chosen here not only because they have been extensively applied in the extraction, reduction and analysis of PNP, 23,[25][26][27][28][29][30][31][32][33][34][35] but also because they provide an ideal solvent environment to improve the uorescence properties of europium complexes. [42][43][44][45] In the course of better detection performance, we synthesized the lanthanide complex Na 3 [-Eu(DPA) 3 ] (abbreviated as Eu[III], DPA ¼ 2,6-pyridinedicarboxylic acid; Fig.…”