Inserting a crystalline P(VDF-TrFE) intermediate layer under rhodamine
6G (R6G) laser active waveguide layer preserved the emissive R6G molecules
in the matrix, which increases the intensity of fluorescence of R6G
dye in the matrix and thus enhances the laser performance, including
the optical gain of amplified spontaneous emission (ASE). The thermal
annealing of the intermediate layer of P(VDF-TrFE) affects the optical
gain of ASE and the laser performance in terms of slope efficiency
and the threshold for the R6G/CA waveguide laser devices with DFB
and DBR structures. With a higher annealing temperature, the crystallinity,
crystallite size, and thus surface roughness of the P(VDF-TrFE) layer
were increased; simultaneously, the fluorescence intensity, the optical
gain of ASE, and the slope efficiency were increased, and the threshold
for lasing was reduced. Thermal annealing of P(VDF-TrFE) at 120 °C
gave a higher crystallinity, larger crystallite size, and thus deeper
surface roughness. A DBR laser device with m = 2
mode number gave a slope efficiency of 4.6% and the optical gain of
ASE of 13.0 cm–1. The deeper roughness of the surface
due to the larger polar β-crystallites of P(VDF-TrFE) was significantly
related to the increased intensity of fluorescence, optical gain of
ASE, and slope efficiency for laser emission and the reduced threshold
for lasing. The present approach is the easier way to enhance the
lasing performances for ionic laser dyes in industrial applications.