Advances in energy storage and energy conversion play an essential role nowadays because the energy demands are becoming greater than ever. To overcome the actual performances of the materials used to build supercapacitors, a combination of transition metal dichalcogenides (TMDCs) and graphene oxide (GO) or reduced graphene oxide (rGO) as graphene-based structures are often studied for their excellent properties, such as high specific area and good electrical conductivity. Nevertheless, synthesis pathways and parameters play key roles in obtaining better materials as components for supercapacitors with higher technical performances. Driven by the desire to understand the influence of the structural and morphological particularities on the performances of supercapacitors based on MoS2/graphene oxide (GO) composites, a survey of the literature was performed by pointing out the alterations induced by different synthesis pathways and key parameters to the above-mentioned particularities.