“…Bulk Bi 2 Te 3 ‐based alloys, the only commercialized TE materials, [ 22 , 23 , 24 ] have generally been employed as TE legs in wearable TEGs, [ 25 , 26 , 27 , 28 , 29 , 30 , 31 , 32 , 33 , 34 , 35 , 36 , 37 , 38 , 39 ] which however are naturally brittle near room temperature. To realize the wearability of electronic devices, the brittle Bi 2 Te 3 ‐based TE legs are generally encapsulated in flexible substrates, [ 25 , 26 , 27 , 28 , 29 ] such as polydimethylsiloxane (PDMS) and Ecoflex.…”