“…Together with previous results, a more complete picture for the optical transitions involving cation vacancy related deep centers in AlGaN alloy system has been constructed. Al-rich AlGaN and AlN have been the subject of intense research effort during the last decade due to their applications in deep ultraviolet (DUV) photonics, 1-5 surface acoustic wave (SAW) devices, 6,7 and field emitters. 8 The superior physical and chemical properties of AlN, such as ultra-wide direct bandgap, 9,10 high melting point, 11 high thermal conductivity, 12 mechanical strength, and radiation hardness, miscibility with GaN in the entire alloy region, make it technologically important.…”