Humidity sensing has a wide application and receives
intense attention
from a broad spectrum of research areas. In this work, we demonstrated
a robust humidity sensing strategy by loading photoacid HPTS (8-hydroxypyrene-1,3,6-trisulfonic
acid, trisodium salt) into nanopores of hollow mesoporous organosilica
(HMO) capsules. Taking advantage of the capillary condensation of
nanopores, water vapor is enriched, which triggers the fluorescent
color change of HPTS through intermolecular excited-state proton transfer
(ESPT) for humidity sensing. The ESPT induced fluorescent color change
behavior of HPTS loaded in nanopores was comprehensively investigated
by using both steady and picosecond time-resolved fluorescence spectroscopy.
The fabricated humidity sensors exhibit rapid response and recovery,
qualified reversibility, and selectivity, which enable continuous
monitoring of human respiration. Notably, the sensing performance, i.e., sensitivity and response range, can be effectively
tuned by fabricating HMO capsules with properly sized nanopores, which
provides an opportunity to design unique nanostructures of the humidity
sensor for specific applications.