We obtain the numerical solutions for a single electron energy level of a hydrogen impurity confined inside an off-center donor in a spherical quantum dot. The energy spectrum of single electron impurity for off-center donor atom subject to screened Coulomb's attractive potential barrier well is presented. Using B-spline finite element method, we generate a complete set of wavefunctions within the central unit cell, and through the perturbation theory, the whole energy spectrum of an impurity at low temperature can be explored. We find that the energy splitting and different related magnetic quantum number m l , i.e., (n, l, m l ) varies with quantum dot size. This is due to the fact that quantum confinement effect lifts the degeneracy which comes from the Coulomb interaction. On the other hand, the phenomena of energy spectrum splitting under this model is an analogous case, considering that degeneracy of hydrogen energy levels in free space has been lifted by an external magnetic field (Zeeman effect).