Certain applications, such as understanding the influence of bedrock geology on hydrology in complex mountainous settings, demand 3D geological models that are detailed, high-resolution, accurate, and spatially-extensive. However, developing models with these characteristics remains challenging. Here, we present a dataset corresponding to a renowned tectonic entity in the Swiss Alps - the Nappe de Morcles - that does achieve these criteria. Locations of lithological interfaces and formation orientations were first extracted from existing sources. Then, using state-of-the-art algorithms, the interfaces were interpolated. Finally, an iterative process of evaluation and re-interpolation was undertaken. The geology was satisfactorily reproduced; modelled interfaces correspond well with the input data, and the estimated volumes seem plausible. Overall, 18 formations, including their associated secondary folds and selected faults, are represented at 10 m resolution. Numerous environmental investigations in the study area could benefit from the dataset; indeed, it is already informing integrated hydrological (snow/surface-water/groundwater) simulations. Our work demonstrates the potential that now exists to develop complex, high-quality geological models in support of contemporary Alpine research, augmenting traditional geological information in the process.