<i>N</i>,<i>N</i>-Dimethylformamide-stabilised palladium nanoparticles combined with bathophenanthroline as catalyst for transfer vinylation of alcohols from vinyl ether

Tabaru, Kazuki; Nakatsuji, Masato; Itoh, Satoshi; Suzuki, Takeyuki; Obora, Yasushi

doi:10.1039/d1ob00369k

Cited by 7 publications

(2 citation statements)

References 48 publications

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“…The size increase and aggregation of the metal nanoparticles would decrease the catalytic activity during the recycling process. 19,20 Fig. 7 shows the time-dependent production of intermediates and the desired products during the Guerbet reaction.…”

Section: Resultsmentioning

confidence: 99%

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N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols

et al. 2022

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Section: Resultsmentioning

confidence: 99%

“…The size increase and aggregation of the metal nanoparticles would decrease the catalytic activity during the recycling process. 19,20…”

Section: Resultsmentioning

confidence: 99%

N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols

et al. 2022

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Catalytic Transfer Vinylation of Alcohols

Opačak,

Tin

2024

Adv Synth Catal

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This review focuses on summarising the studies on transition metal catalysed transfer vinylation of alcohols using vinyl ethers and vinyl acetate as vinylating agents. Mercury, palladium, iridium and gold catalysts are discussed herein. Selected examples from publications and patents are given for the purpose of analysing functional group tolerance towards the methodology. In addition, mechanistic pathways are described.

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The Vinyl Group: Small but Mighty – Transition Metal Catalyzed and Non‐Catalyzed Vinylation Reactions

Papaplioura,

Mercier,

Jerhaoui

et al. 2024

ChemCatChem

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Transition metal catalysis allows for the efficient and selective introduction of vinyl moieties onto organic molecules and offers a versatile approach to synthesizing complex organic molecules. Nonetheless, few transition‐metal free vinylation reactions have also been reported, exhibiting exceptional functional group tolerance and circumventing selectivity issues. This review provides an overview of carbon, nitrogen and oxygen vinylation, presenting innovative strategies and key advancements in the field. Hence, it will serve as a valuable resource for organic chemists who are interested in the synthesis of vinyl‐containing compounds. By understanding the diverse strategies involved in vinylation, readers will gain insights into harnessing this powerful synthetic methodology for the efficient construction of carbon‐carbon and carbon‐heteroatom bonds.

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N,N-Dimethylformamide-stabilised palladium nanoparticles combined with bathophenanthroline as catalyst for transfer vinylation of alcohols from vinyl ether

Abstract: We report N,N-dimethylformamide-stabilised Pd nanoparticles (Pd NPs)-catalysed transfer vinylation of alcohols from vinyl ether. Pd NPs combined with bathophenanthroline exhibited high catalytic activity. This reaction proceeded with low catalyst loading...

Cited by 7 publications

References 48 publications

N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols

N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols

Catalytic Transfer Vinylation of Alcohols

The Vinyl Group: Small but Mighty – Transition Metal Catalyzed and Non‐Catalyzed Vinylation Reactions

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