S-Methyltrans-cis-β-N-(2-hydroxynaphthyl)methylenedithiocarbazate

Abstract

In the title compound, C13H12N2OS2, the whole mol­ecule is nearly planar. The mol­ecules are linked by N—H⋯S hydrogen bonds between the amino group and the thione S atoms, forming molecular chains along the a direction.

2-[(1E)-({[(Benzylsulfanyl)methanethioyl]amino}imino)methyl]-6-methoxyphenol: crystal structure and Hirshfeld surface analysis

“…There are three examples, II-IV, of derivatives with a hydroxy group in the 2-position of the ring connected to the imine-C atom (Madanhire et al, 2015;Sethuraman et al, 2002;Begum et al, 2016), with their chemical diagrams shown in Scheme 2. Interestingly, there are four virtually identical molecules comprising the asymmetric unit in IV (Begum et al, 2016).…”