trans-Diaquabis(ethylenediamine)zinc(II) 2-(sulfanilamido)pyrimidine monohydrate

Abstract

In the title compound, [Zn(C4H8N4)(H2O)2](C10H9N4O2S)2·H2O, the ZnII ion is octa­hedrally surrounded by two water O atoms [Zn—O = 2.68 (2) and 2.49 (2) Å] and the four N atoms of two ethylenediamine mol­ecules. Inter­molecular O—H⋯N, N—H⋯O and N—H⋯N hydrogen‐bond inter­actions result in the formation of an intricate three‐dimensional network.

New Water‐Soluble Cluster Compound {Zn(en)3}3[V15Sb6O42(H2O)]⋅ (Ethylenediamine)3⋅10 H2O as a Synthon for the Generation of Two New Antimonato Polyoxovanadates

“…Zn(3) is surrounded by two en ligands (Zn−N bonds: 1.973(10)–2.018(9) Å; average: 2.003 Å) forming a distorted tetrahedron (N−Zn−N angles: 85.9(4)–128.0(4)°) (Figure ; Tables S4–S6). All angles and bond lengths are in full agreement with literature data for Zn‐containing POVs and other zinc ethylenediamine complexes …”

“…The bite angle for the en ligands connecting the cluster is 82.4(2)°. The corresponding angle of 97.6(2)° between these two en ligands is in line with literature data . The second unique Zn 2+ cation is in a distorted octahedral environment made up of three bidentate phen ligands (Tables S3, S5, and S6).…”

Butylammonium sulfadiazinate monohydrate

“…The zinc(II) complex of sulfadiazine is used to prevent bacterial infection in burned animals (Brown et al, 1987). Interesting structural results have been described in the literature (Baenziger et al, 1983;Garcia Raso et al, 1997;Işık et al, 2005). In this paper, we report the crystal structure of the title salt, (I).…”

Diaquabis(ethylenediamine-κ2N,N′)zinc(II) bis(4-aminonaphthalene-1-sulfonate) dihydrate

“…For related literature, see: Gunderman et al (1997); Işık et al (2005); Kosnic et al (1992); Shubnell et al (1994).…”