“…The application of Zr-MOF powders is greatly hampered, due to their inherent problems such as particle aggregation, poor processability and handling, mass transfer limitations, and signicant pressure drop in an adsorption bed. [11][12][13][14][15] To overcome the issues of Zr-MOF powders, many methods have been reported to construct Zr-MOF macroscale structures by either integrating Zr-MOFs into support materials such as bers, [16][17][18] polymeric monoliths 19,20 and foams, [21][22][23] or pelletizing Zr-MOF powders via mechanical compression or extrusion. [24][25][26] However, both strategies still have issues such as reduced adsorption capacities, due to the use of Zr-MOF as a secondary component, and pressure-induced losses of crystallinity and porosity.…”