Iminoxyle Radical with Isocyanide as a Spin Label for Haemoproteins

Reichman, L.M.; Annaev, B; Belova, V S; Rozantzev, E.G.

doi:10.1038/newbio237031b0

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Anions and Their Reactivity With Cluster C1

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“…n -Butyl isocyanide ( n -BIC) was found to behave as a CO analog at both the CODH and ACS active sites . Isocyanides [RNC] , are isoelectronic with CO and have used for many years as CO analogs for heme proteins. − They are stable organic compounds that formally possess a divalent carbon and can behave as strong carbon ligands for transition metals. Since the negative charge is on the terminal carbon, isocyanides have a tendency to form cationic species and can stabilize high oxidation states of metal ions.…”

Section: Anions and Their Reactivity With Cluster Cmentioning

confidence: 99%