2004
DOI: 10.1126/science.1097329
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Impact of Anthropogenic CO 2 on the CaCO 3 System in the Oceans

Abstract: Rising atmospheric carbon dioxide (CO2) concentrations over the past two centuries have led to greater CO2 uptake by the oceans. This acidification process has changed the saturation state of the oceans with respect to calcium carbonate (CaCO3) particles. Here we estimate the in situ CaCO3 dissolution rates for the global oceans from total alkalinity and chlorofluorocarbon data, and we also discuss the future impacts of anthropogenic CO2 on CaCO3 shell-forming species. CaCO3 dissolution rates, ranging from 0.0… Show more

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Cited by 2,051 publications
(1,366 citation statements)
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References 32 publications
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“…[12] These distribution patterns were generally the same as those determined by using data collected in 1993, and those for the central Pacific (WHP P15) reported by Feely et al [2004]. Figure 1) mostly on isopycnal surfaces above the saturation horizon; negative DW arg values (i.e., decreases in the saturation state) were dominant.…”
Section: Distributions Of Caco 3 Saturation Statessupporting
confidence: 77%
See 1 more Smart Citation
“…[12] These distribution patterns were generally the same as those determined by using data collected in 1993, and those for the central Pacific (WHP P15) reported by Feely et al [2004]. Figure 1) mostly on isopycnal surfaces above the saturation horizon; negative DW arg values (i.e., decreases in the saturation state) were dominant.…”
Section: Distributions Of Caco 3 Saturation Statessupporting
confidence: 77%
“…Observed increases in CO 2 concentrations in the atmosphere, together with increases in concentrations of other greenhouse gases, very likely cause so-called global warming. Although the ocean tends to moderate global warming by absorbing anthropogenic CO 2 from the atmosphere, that very absorption leads to ocean acidification [Feely et al, 2004;Orr et al, 2005].…”
Section: Introductionmentioning
confidence: 99%
“…Many marine organisms are very sensitive to changes in ocean CO 2 chemistry -especially those biota that use carbonate ions dissolved in the sea water to form protective calcium carbonate shells or skeletal structures. Surface ocean pH has decreased by about 0.1 pH units (corresponding to a 30% increase in hydrogen ion concentration and a 16 % decline in carbonate concentrations) since pre-industrial times (Guinotte et al 2003;Feely et al, 2004;Orr et al, 2005;Guinotte & Fabry, 2008;Doney et al, 2009). This rate of acidification is at least 100 times faster than at any other time in the last 20 million years.…”
Section: Ocean Acidificationmentioning
confidence: 99%
“…The CaCO 3 saturation state (W) is defined as the product of the concentrations of the carbonate ion [CO 3 2− ] and the ] to the stoichiometric solubility product primarily govern the degree of CaCO 3 saturation state [Feely et al, 2004]. The saturation state of seawater for CaCO 3 is a measure of its potential to corrode the CaCO 3 shells and skeletons of marine organisms.…”
Section: Introductionmentioning
confidence: 99%