Improved Multianalyte Determination of the Intense Sweeteners Aspartame and Acesulfame‐K with a Solid Sensing Zone Implemented in an FIA Scheme

García‐Jiménez, J. F.; Valencia, M. C.; Capitán-Vallvey, L.F.

doi:10.1080/00032710600666487

Cited by 17 publications

(3 citation statements)

References 15 publications

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“…The most popular choice for the determination of additives is high-performance liquid chromatography (HPLC) [4][5][6][7][8][9], but also other analytical methods have been applied in their analysis [10][11][12][13]. However, food additives analyses using HPLC Corona CAD are scarce up to date [14].…”

Section: Introductionmentioning

confidence: 99%

Simultaneous determination of aspartame, acesulfame-K, saccharin, citric acid and sodium benzoate in various food products using HPLC–CAD–UV/DAD

Grembecka

Baran

Błażewicz

et al. 2013

Eur Food Res Technol

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Section: Introductionmentioning

confidence: 99%

Simultaneous determination of aspartame, acesulfame-K, saccharin, citric acid and sodium benzoate in various food products using HPLC–CAD–UV/DAD

Grembecka

Baran

Błażewicz

et al. 2013

Eur Food Res Technol

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“…At pHs other than this value, the surface charge of MOF is charged. On the other hand, isoelectric point of ASP was determined as 5.25 (pK 1 3.18, pK 2 7.82) [33]. At pH around 6, MOF is positively charged, while ASP is in anionic form, therefore recovery increases.…”

Section: Effect Of Phmentioning

confidence: 99%

PCN-222 metal–organic framework: a selective and highly efficient sorbent for the extraction of aspartame from gum, juice, and diet soft drink before its spectrophotometric determination

et al. 2020

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In this paper, we describe synthesis and application of an iron porphyrinc metal-organic framework PCN-222(Fe) for solid phase extraction of aspartame, an artificial non-saccharine sweetener, from gum, juice and diet soft drink samples prior to its determination by spectrophotometry. The mesoporous MOF was synthesized solvo-thermally and characterized by Fourier transform-infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, and Brunauer-Emmett-Teller techniques. To obtain the best extraction efficiency of aspartame, significant affecting parameters such as pH of sample solution, amount of the sorbent, type and volume of eluting solvent, and adsorption and desorption times were investigated and optimized. Under optimum conditions, the calibration graph for aspartame was linear in the range of 0.1 to 100.0 mg.L −1 and relative standard deviation of aspartame was 1.7% (n = 7). Limit of detection of method calculated as 0.019 mg.L −1 and the enrichment factor of 350 folds was obtained. Adsorption capacity of synthesized sorbent was found to be 356 mg.g −1. Hierarchical porosity, the eight terminal-OH groups of the Zr 6 node, and hydrogen bonding possibly play vital role for selective adsorption of aspartame. The optimized method was successfully applied to the determination of aspartame in real samples with reasonable recoveries (> 98%).

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“…FI-SPS is also applicable to the analysis of organic or inorganic chemical components in food samples. (N-L-α-aspartyl-Lphenylalanine-1-methyl ester) (AS) in sweets and drinks [88], and Acesulfame-K (6-methyl-1,2,3-oxathiazin-4(3H)-one-2,2-dioxide) (AK) in tabletop sweeteners [89]. Their FI-SPS system was also used for the determination of AS in low-calorie foods and dietary products [90] and SA in low-calorie foods, but without separation [91].…”

Section: Foodmentioning

confidence: 99%

Recent trends in solid phase spectrometry: 2003–2009. A Review

Matsuoka

Yoshimura

2010

Analytica Chimica Acta

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Around 100 papers published from 2003 to the present are reviewed concerning analytical methods for the direct light measurement of a solid phase in which a target colored or fluorescent analyte is concentrated. Recent attention has been paid to the development of flow injection-solid phase spectrometry as a simple and inexpensive tool for routine analysis of organic compounds or pharmaceuticals. Due to some improvements in flow injection analysis, such as sequential injection and lab-on-a-valve, it is possible not only to reduce the reagent consumption but also to devise fully automatic and miniaturized systems with minimal maintenance needs. This may have the potential of becoming one of the green analytical methods. Flow injection-solid phase spectrometry is expected to be applied to the speciation of trace chemical components (e.g., specific determination of trace metal ions in different existent oxidation states) in real samples in the environment.

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Improved Multianalyte Determination of the Intense Sweeteners Aspartame and Acesulfame‐K with a Solid Sensing Zone Implemented in an FIA Scheme

Cited by 17 publications

References 15 publications

Simultaneous determination of aspartame, acesulfame-K, saccharin, citric acid and sodium benzoate in various food products using HPLC–CAD–UV/DAD

Simultaneous determination of aspartame, acesulfame-K, saccharin, citric acid and sodium benzoate in various food products using HPLC–CAD–UV/DAD

PCN-222 metal–organic framework: a selective and highly efficient sorbent for the extraction of aspartame from gum, juice, and diet soft drink before its spectrophotometric determination

Recent trends in solid phase spectrometry: 2003–2009. A Review

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