A review has been presented detailing the comparisons between numerical prediction and experimental data collected in the LENS facilities for a program focusing on thermochemical modeling of the flow in the reflected shock tunnel facility at high enthalpy. Comparisons have been provided for several studies made in the LENS-I facility including fundamental laser diode measurements of freestream nitric oxide concentration, temperature, and velocity; measurements on a two-dimensional cylinder; and measurements of laminar shock-wave/boundary layer interaction on a double cone geometry. The freestream velocity of the facility is found to be predicted to an accuracy of 2.5% or better for well-tailored conditions at all enthalpy levels, but the static temperature is significantly over-predicted for high enthalpy flows. Despite this, good agreement is obtained with all measurements for a two-dimensional cylinder. For the double cone model, the effect of vibration-dissociation coupling with the T-T V and CVDV models has been investigated. The choice of coupling model has impact for the lower enthalpy case, but in the high enthalpy case, it is unclear whether the discrepancy with the measurements is attributable to the coupling in the interaction region or the understanding of the freestream conditions.