In order to improve the understanding of the microphysical characteristics of raindrop size distribution (DSD) under different rainfall rates (R) classes, and broaden the knowledge of the impact of radar wavelengths and R classes on the QPE of dual-polarization radars in the Tianshan Mountains, a typical arid area in China, we investigated the microphysical characteristics of DSD across R classes and dual-polarimetric radar QPE relationships across radar wavelengths and R classes, based on the DSD data from a PARSIVEL2 disdrometer at Zhaosu in the Tianshan Mountains during the summers of 2020 and 2021. As the R class increased, the DSD became wider and flatter. The mean value of the mass-weighted mean diameters (Dm) increased, while the mean value of logarithm normalized intercept parameters (log10 Nw) decreased after increasing from C1 to C3, as the R class increased. The largest contributions to R and the radar reflectivity factor from large raindrops (diameter > 3 mm) accounted for approximately 50% and 97%, respectively, while 84% of the total raindrops were small raindrops (diameter < 1 mm). Dual-polarization radars—horizontal polarization reflectivity (Zh), differential reflectivity (Zdr), and specific differential phase (Kdp)—were retrieved based on the DSD data using the T-matrix scattering method. The DSD-based polarimetric radar QPE relations of a single-parameter (R(Zh), R(Kdp)), and double-parameters (R(Zh,Zdr), R(Kdp,Zdr)) on the S-, C-, and X-bands were derived and evaluated. Overall, the performance of the R(Kdp) (R(Kdp,Zdr)) scheme was better than that of R(Zh) (R(Zh,Zdr)) for the QPE in the three bands. Furthermore, we have for the first time confirmed and quantified the performance differences in the QPE relationship of dual-polarization radars under different schemes, radar wavelengths, and R classes in typical arid areas of China. Therefore, selecting an appropriate dual-polarization radar band and QPE scheme for different R classes is necessary to improve the QPE ability compared with an independent scheme under all R classes.