Light-emitting diodes (LEDs), including organic LEDs and polymer LEDs, have been studied intensively for use in displays and interior lighting due to their promising advantages of high effi ciency, high contrast ratio, long lifetime and low power consumption. [ 1 , 2 ] However, in a conventionally structured LED, less than 20% of the generated light is emitted as useful radiation. [ 3 , 4 ] Not surprisingly, the improvement of light extraction effi ciency is currently considered to be one of the most important issues for LED research. A variety of strategies have been suggested towards this end, including modifi ed substrates, microlenses, silica microspheres, silica aerogels [5][6][7][8] and twodimensional (2D) photonic crystals (PhCs). [9][10][11] Inverse opals (IO) [ 12 , 13 ] are one of the most promising approaches to realization of a 2D PhC structure. [ 14 , 15 ] To date, most of the reported 2D IOs have been fabricated with open top-surface structures. However, it is diffi cult to deposit thin layers for fabrication of LEDs onto the mesoporous structure and to attain a high refractive index contrast to raise effi cient diffraction of waveguided light. [ 16 ] Moreover, it is desirable that organic materials do not infi ltrate into the air void when IOs with air pockets are inserted between the multiple-layered structure. Thus, it is very challenging to fabricate a 2D IO with closed top-surface structure for further application.Here, we demonstrate experimentally and numerically the enhanced light extraction effi ciency of a polymer LED in which, for the fi rst time, a 2D TiO 2 IO structure is inserted between the glass and anode electrode. Unlike conventional 2D IO structures, the 2D TiO 2 IO structures with closed top-surface have a thin fl at fi lm on top, where thin layers for fabrication of LEDs can conveniently be added easily onto the structure even via a solution process like spin-coating. For enhancing the light extraction from LEDs, this approach is very useful since a 2D PhC pattern can be easily obtained by adopting a simple colloidal assembly technique and sol-gel method. Furthermore, it is convenient to control the period of the 2D PhC pattern just by varying the size of the opal template nanoparticles used in the colloidal assembly process. To estimate the light extraction effi ciency enhancement of the 2D TiO 2 IO structure and investigate the far-fi eld radiation pattern with respect to the periods of the 2D TiO 2 IO structure, we performed three-dimensional fi nite-difference time-domain (3D-FDTD) simulations. [ 17 ] Finally, we confi rmed that the 2D TiO 2 IO structure enhanced the extraction effi ciency by comparing the measured enhancement of the fabricated LED devices with that simulated. Figure 1 shows a schematic diagram of the fabrication of the 2D TiO 2 IO with a closed top-surface structure. The fabrication started with an opal monolayer template using polystyrene (PS) nanoparticles prepared by emulsifi er-free emulsion polymerization. [ 18 ] Using 270 nm PS nanoparticles, an o...