Evidence for photoluminescence band in ptype Al0.67Ga0.33As related to nonequilibrium DX− centers Very high carbon δdoping concentration in Al x Ga1−x As grown by metalorganic vapor phase epitaxy using trimethylaluminum as a doping precursor Highly carbon-doped Ga 0.47 In 0.53 As layers grown by chemical beam epitaxy have been exposed to a deuterium plasma. Deuterium diffusion profiles reflect very strong C-D interactions. Concerning electronic transport properties, from p-type when as-grown, these GaInAs samples turn to n-type after plasma exposure. Annealings of deuterated layers have also been performed. They show that temperatures as high as 450°C must be reached before p-type conductivity is fully restored in the material.