Indium tert-butylthiolates as single source precursors for indium sulfide thin films: Is molecular design enough?

MacInnes, Andrew N.; Power, Michael B.; Hepp, Aloysius F.; Barron, Andrew R.

doi:10.1016/0022-328x(93)80111-n

Cited by 59 publications

(31 citation statements)

References 35 publications

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“…The deposition of indium sulphide with this process has not yet been well explored. In the eighties, the MOCVD technique was applied to deposit indium sulphide using singlesource precursors [7]. The disadvantages of using single sources are limited process control and high decomposition temperatures.…”

Section: Introductionmentioning

confidence: 99%

MOCVD indium sulphide for application as a buffer layer in CIGS solar cells

et al. 2009

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Section: Introductionmentioning

confidence: 99%

MOCVD indium sulphide for application as a buffer layer in CIGS solar cells

et al. 2009

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“…More recently in the search for 2D materials beyond graphene, the InS phase has gained considerable interest, particularly in the form of a two atom‐thin layered material or two‐dimensional (2D) nanomaterial. However, synthetic chemical routes rarely produces crystalline InS, and any heating usually induces a phase change to the thermodynamically stable In 2 S 3 species . The In 2 S 3 phase exists in three polymorphic forms, i.e.…”

Section: Introductionmentioning

confidence: 99%

Important Phase Control of Indium Sulfide Nanomaterials by Choice of Indium(III) Xanthate Precursor and Thermolysis Temperature

et al. 2019

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Four In(III) xanthate complexes, [In(S2COR)3] where R = Me, Et, iPr and sBu, respectively, were synthesized, characterized and subsequently used as single source molecular precursors via a solventless thermolysis route to obtain indium sulfide materials. By choice of precursor and reaction temperature crystalline powders of tetragonal In2S3, cubic In2S3 and cubic In2.77S4 were acquired. The phase identification and purity were conducted through examination of the experimental powder X‐ray diffraction patterns relative to the simulated patterns for single X‐ray crystal diffraction.

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“…Further, the rational chemical design of new ceramics (and inorganic materials in general) is poorly understood. 4 ,5 The performance of polymer-filler composites is strongly dependent on the particle size of the filler, and the interaction between the polymer and filler. The ideal filler then, is stable, hydrophobic, nano-sized, and covalently bound to the matrix.…”

Section: Introductionmentioning

confidence: 99%

Fiber Reinforced Epoxy Resin Composite Materials Using Carboxylate-Alumoxanes as Cross-Linking Agents

1999

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Chemically functionalized alumina nanoparticles (carboxylate-alumoxanes) are used as the inorganic component of a new class of inorganic-organic hybrid materials. Lysine-or parahydroxybenzoic acid-derivatized alumoxanes are readily prepared from the reaction of boehmite, [AI(O)(OH)]n, with the appropriate carboxylic acid. The peripheral organic hydroxides and amines of these carboxylate-alumoxanes either react directly with epoxide resins, such as the diglycidyl ether of bisphenol-A (DER 332), to form a hybrid material, or in the presence of an organic resin and hardener system to form a composite material. SEM and AFM show a uniform distribution of alumina nanoparticles within the resin matrix. The properties and cure times of the alumoxane hybrid and composite materials are distinct from both the pure resins and from a physical blend of the resins with traditional ceramic fillers. A significant increase in thermal stability and tensile strength is observed for both the hybrid and composite resin systems. In addition, both carbon fiber and carbon/Kevlar® matting have been successfully incorporated into the hybrid resin systems resulting in further property improvements.

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Indium tert-butylthiolates as single source precursors for indium sulfide thin films: Is molecular design enough?

Cited by 59 publications

References 35 publications

MOCVD indium sulphide for application as a buffer layer in CIGS solar cells

MOCVD indium sulphide for application as a buffer layer in CIGS solar cells

Important Phase Control of Indium Sulfide Nanomaterials by Choice of Indium(III) Xanthate Precursor and Thermolysis Temperature

Fiber Reinforced Epoxy Resin Composite Materials Using Carboxylate-Alumoxanes as Cross-Linking Agents

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