Influence of minor additions of Si on the crystallization kinetics of Cu55Hf45 metallic glasses

Kinetic Study of Seed-Assisted Crystallization of ZSM-5 Zeolite in an OSDA-Free System Using a Natural Aluminosilicate as Starting Source

“…It shows a sigmoidal curve, typical for zeolites crystallization. As mentioned previously, this behavior can be described by the KJMA model where n can be obtained from the slope of a Sharp–Hancock graph by taking the double logarithm of eq , as expressed in eq …”

Kinetics analysis of the isothermal crystallization of Cu55Zr45 metallic glass by differential scanning calorimetry

“…Crystallization kinetics of Cu 55 Hf 45 and Cu 50 Zr 50 glassy alloy was studied . Meanwhile, influence of minor additions of Si on the crystallization kinetics of Cu 55 Hf 45 metallic glasses was reported . In this paper, the isothermal crystallization of Cu 55 Zr 45 binary glassy alloy will be investigated to further understand the crystallization process of binary glassy alloy.…”

“…13,14 Meanwhile, influence of minor additions of Si on the crystallization kinetics of Cu 55 Hf 45 metallic glasses was reported. 15 In this paper, the isothermal crystallization of Cu 55 Zr 45 binary glassy alloy will be investigated to further understand the crystallization process of binary glassy alloy. In isothermal crystallization condition, metallic glass is heated to the annealing temperatures to hold for a period of time for crystallization at a constant rate.…”

Heredity of clusters in the rapidly cooling processes of Al-doped Zr50Cu50 melts and its correlation with the glass-forming ability*

“…[4] Researchers have improved the GFA and developed new BMGs by adding small amounts of alloying element(s) starting from the best binary glass-forming alloys. [5][6][7][8] For example, Figueroa et al [9] found that the GFA of Cu 55 Hf 45 alloys could be maximized with the addition of 2.0-at.% Si, and that the supercooled liquid region was increased by 15 K relative to the matrix alloy. Cai et al [6] revealed that the substitution of Zr in Cu 50 Zr 50 alloy by Al could remarkably increase the GFA, and the best glass-forming alloy was Cu 50 Zr 47 Al 3 .…”

“…Cai et al [6] revealed that the substitution of Zr in Cu 50 Zr 50 alloy by Al could remarkably increase the GFA, and the best glass-forming alloy was Cu 50 Zr 47 Al 3 . The increase in GFA via minor doping has been explained using methods involving thermodynamics (e.g., thermal stability) [9,10] and kinetics (e.g., dynamic slowing down). [11] However, the atomic structural mechanism of the GFA of element-doped liquid alloys remains poorly understood because of experimental limitations.…”